Some group VB chloride complexes with thiourea and N,N′-diethyl-dithiooxamide
Date
1979Author
Wandiga, Shem O
Jenkins, Linda S
Willey, Gerald R
Type
ArticleLanguage
enMetadata
Show full item recordAbstract
The following complexes of thiourea(tu) and N,N′-diethyl-dithioxamide (Et2DH2) with phosphorous (III), arsenic(III), antimony(III) and bismuth(III) have been prepared and characterises: PCl3(tu) (DMF)2; AsCl3(tu)3(DMSO)3: MCl3(tu)3 (M = As, Bi); SbCl3(tu)2(DMF) and SbCl3(Et2DH2)1.5 (C2H4Cl2). IR and NMR (1H, 13C and 31P) spectral data provides evidence for ligand attachment exclusively by sulphur coordination in all complexes excepting PCl3(tu) (DMF)2. For the latter additional metal-nitrogen bonding is proposed.
URI
http://www.sciencedirect.com/science/article/pii/0022190279800676http://erepository.uonbi.ac.ke:8080/xmlui/handle/123456789/34076
Citation
Journal of Inorganic and Nuclear Chemistry Volume 41, Issue 7, 1979, Pages 941–945Publisher
University of Nairobi Department of Chemistry, Department of Chemistry and Molecular Sciences, University of Warwick