dc.contributor.author | Wandiga, Shem O | |
dc.contributor.author | Jenkins, Linda S | |
dc.contributor.author | Willey, Gerald R | |
dc.date.accessioned | 2013-06-14T14:41:39Z | |
dc.date.available | 2013-06-14T14:41:39Z | |
dc.date.issued | 1979 | |
dc.identifier.citation | Journal of Inorganic and Nuclear Chemistry Volume 41, Issue 7, 1979, Pages 941–945 | en |
dc.identifier.uri | http://www.sciencedirect.com/science/article/pii/0022190279800676 | |
dc.identifier.uri | http://erepository.uonbi.ac.ke:8080/xmlui/handle/123456789/34076 | |
dc.description.abstract | The following complexes of thiourea(tu) and N,N′-diethyl-dithioxamide (Et2DH2) with phosphorous (III), arsenic(III), antimony(III) and bismuth(III) have been prepared and characterises: PCl3(tu) (DMF)2; AsCl3(tu)3(DMSO)3: MCl3(tu)3 (M = As, Bi); SbCl3(tu)2(DMF) and SbCl3(Et2DH2)1.5 (C2H4Cl2). IR and NMR (1H, 13C and 31P) spectral data provides evidence for ligand attachment exclusively by sulphur coordination in all complexes excepting PCl3(tu) (DMF)2. For the latter additional metal-nitrogen bonding is proposed. | en |
dc.language.iso | en | en |
dc.publisher | University of Nairobi | en |
dc.title | Some group VB chloride complexes with thiourea and N,N′-diethyl-dithiooxamide | en |
dc.type | Article | en |
local.publisher | Department of Chemistry, | en |
local.publisher | Department of Chemistry and Molecular Sciences, University of Warwick | en |