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dc.contributor.authorWandiga, Shem O
dc.contributor.authorJenkins, Linda S
dc.contributor.authorWilley, Gerald R
dc.date.accessioned2013-06-14T14:41:39Z
dc.date.available2013-06-14T14:41:39Z
dc.date.issued1979
dc.identifier.citationJournal of Inorganic and Nuclear Chemistry Volume 41, Issue 7, 1979, Pages 941–945en
dc.identifier.urihttp://www.sciencedirect.com/science/article/pii/0022190279800676
dc.identifier.urihttp://erepository.uonbi.ac.ke:8080/xmlui/handle/123456789/34076
dc.description.abstractThe following complexes of thiourea(tu) and N,N′-diethyl-dithioxamide (Et2DH2) with phosphorous (III), arsenic(III), antimony(III) and bismuth(III) have been prepared and characterises: PCl3(tu) (DMF)2; AsCl3(tu)3(DMSO)3: MCl3(tu)3 (M = As, Bi); SbCl3(tu)2(DMF) and SbCl3(Et2DH2)1.5 (C2H4Cl2). IR and NMR (1H, 13C and 31P) spectral data provides evidence for ligand attachment exclusively by sulphur coordination in all complexes excepting PCl3(tu) (DMF)2. For the latter additional metal-nitrogen bonding is proposed.en
dc.language.isoenen
dc.publisherUniversity of Nairobien
dc.titleSome group VB chloride complexes with thiourea and N,N′-diethyl-dithiooxamideen
dc.typeArticleen
local.publisherDepartment of Chemistry,en
local.publisherDepartment of Chemistry and Molecular Sciences, University of Warwicken


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